GIMP Portable 2.6.6 is a portable, freeware image editing tool that ships with some useful features and can be launched from a USB stick or other portable device. This application is equipped with all the usual image editing tools and is capable of performing most tasks you'd expect from an application of its size. The application supports an array of file formats and even supports some Photoshop plug-ins.
GIMP Portable 2.6.6 link.
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