A group of engineers at MIT has developed a new type of membrane for one type
of fuel cell which they claim could improve power output by more than 50 per
cent.
The new material is considerably less expensive than its conventional
industrial counterpart, and could help fuel cells to find a much broader market,
particularly in portable electronics.
"Our goal is to replace traditional fuel-cell membranes with these
cost-effective, highly tuneable and better-performing materials," said Paula T.
Hammond, Bayer Professor of Chemical Engineering at MIT, and leader of the
research team.
The team focused on direct methanol fuel cells (DMFCs) in which the methanol
is directly used as the fuel. Reforming of alcohol down to hydrogen is not
required.
Such a fuel cell is attractive because the only waste products are water and
carbon dioxide, the latter produced in small quantities.
Also, because methanol is a liquid, it is safer and easier to store and
transport than hydrogen gas.
Our goal is to replace traditional fuel-cell membranes with these better-performing materials
Paula T. Hammond MIT
However, DMFCs on the market have limitations as the material currently used
for the electrolyte, known as Nafion, is expensive.
Furthermore Nafion is permeable to methanol allowing some of the fuel to seep
across the centre of the fuel cell, thereby wasting fuel and lowering the
efficiency of the cell.
Using a relatively new technique known as layer-by-layer assembly, the MIT
researchers created an alternative to Nafion which is two orders of magnitude
less permeable to methanol but compares favourably to Nafion in proton
conductivity.
To test their creation, the engineers coated a Nafion membrane with the new
film and incorporated the whole into a direct methanol fuel cell. The result was
an increase in power output of more than 50 per cent.
The team is now exploring whether the new film could be used by itself,
completely replacing Nafion.
Hammond noted that the new material also has potential for use in other
electrochemical systems such as batteries, and that the team has begun exploring
the new material's potential use in photovoltaics.
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