Researchers at the National Institute of Standards and Technology (Nist) have
identified an "evolutionary link" between today's microelectronics built from
semiconductor compounds, and future generations of devices made largely from
complex organic molecules.
A forthcoming paper in the Journal of the American Chemical Society
will demonstrate that a single layer of organic molecules can be assembled on
the same sort of substrate used in conventional microchips.
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The ability to use a silicon crystal substrate that is compatible with the
industry-standard CMOS (complementary metal oxide semiconductor) manufacturing
technology paves the way for hybrid CMOS-molecular device circuitry.
This is the necessary precursor to a "beyond CMOS", totally molecular
technology, according to the Nist researchers.
The team first demonstrated that a good quality monolayer of organic
molecules could be assembled on the silicon orientation common to industrial
CMOS fabrication.
They then built a simple but working molecular electronic device - a resistor
- using the same techniques.
The team fabricated two molecular electronic devices, each with a different length of carbon chain populating the monolayer
National Institute of Standards and Technology
A single layer of simple chains of carbon atoms tethered on the ends with
sulphur atoms were deposited in tiny 100nm-deep wells on the silicon substrate
and capped with a layer of silver to form the top electrical contact.
"The Nist team fabricated two molecular electronic devices, each with a
different length of carbon chain populating the monolayer," the scientists
reported.
"Both devices successfully resisted electrical flow with the one possessing
longer chains having the greater resistance as expected.
"A control device lacking the monolayer showed less resistance, proving that
the other two units functioned as nonlinear resistors."
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